from what ive seen, barrel length doesn't have much to do with accuracy...what you said about moving the gun more before the projectile leaves the gun is more of a shooter issue, and just requires technique to repeat patterns. ppl usually look at barrel length more when thinking about velocity, like with a pcp, the larger, the faster, but with spring guns, the pellet with be at its fastest at around the first 10-12 inches of the barrel, and it slows down for the rest of the trip to the muzzle. most unmodified co2 guns use up all their co2 within the first 15-18 inches, so getting a 24" barrel on a stock 2250 will just hurt a guns velocity...but if you let more gas through the gun with the shot(get it modified) then it will take longer for the gas to fully expand, so a 24" barrel is most desired.
hope this helps you out, and helps the discussion get rolling a bit, cuz i aggree with gene...this could get interesting.
Dave